Molecular spectroscopy and chirality
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Scope of this subject
This cluster of papers focuses on the application of chiroptical spectroscopic methods, such as vibrational circular dichroism and optical rotation, combined with computational techniques like density functional theory and NMR, for the determination of absolute configuration, conformational analysis, and stereochemistry in organic compounds, particularly natural products. The cluster also explores the role of chiroptical spectroscopy in structure elucidation and its use in studying the chiral properties of molecules.
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Research vocabulary
optical activity; chiral molecules; optical rotation; vibrational circular dichroism; optical rotatory dispersion; chiroptical properties; Cotton effect; Raman optical activity; configuration assignment; stereochemical assignment; chiroptical spectroscopy; natural product stereochemistry; vicinal coupling constants; rotational strength; chiral shift reagents; chiral solvating agents; configuration determination; absolute configuration determination; enantiomeric excess determination; chiral solvents; lanthanide shift reagents; stereochemistry determination; exciton chirality; vibrational optical activity; lanthanide-induced shifts
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Morton address: 38285306465782869 · morton4x16-v1
Coordinates: (3, 16, 1607, 12748). The address interleaves categorical identifier bits. Nearby addresses are not guaranteed to describe semantically similar subjects.
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