{"cited_by_count":193381,"description":"This cluster of papers focuses on recent advances in superelectrophilic chemistry, including the synthesis and application of sultams, superacid-catalyzed reactions, intramolecular cyclization, polymer synthesis, asymmetric synthesis, and the use of Lewis acids in various electrophilic reactions.","display_name":"Organic and Inorganic Chemical Reactions","domain_id":"3","external_ids":{"openalex":"https://openalex.org/T14068","wikipedia":"https://en.wikipedia.org/wiki/Electrophile"},"field_id":"16","id":"T14068","keywords":[{"display_name":"Friedel-Crafts alkylation","id":"friedel-crafts-alkylation","score":0.2159,"url":"https://openalex.org/keywords/friedel-crafts-alkylation"},{"display_name":"carbocations","id":"carbocations","score":0.2348,"url":"https://openalex.org/keywords/carbocations"},{"display_name":"Friedel-Crafts reaction","id":"friedel-crafts-reaction","score":0.2817,"url":"https://openalex.org/keywords/friedel-crafts-reaction"},{"display_name":"carbocation stability","id":"carbocation-stability","score":0.3141,"url":"https://openalex.org/keywords/carbocation-stability"},{"display_name":"superacids","id":"superacids","score":0.5932,"url":"https://openalex.org/keywords/superacids"},{"display_name":"antimony pentafluoride","id":"antimony-pentafluoride","score":0.2741,"url":"https://openalex.org/keywords/antimony-pentafluoride"},{"display_name":"fluorosulfonic acid","id":"fluorosulfonic-acid","score":0.3619,"url":"https://openalex.org/keywords/fluorosulfonic-acid"},{"display_name":"superacid catalysis","id":"superacid-catalysis","score":0.5188,"url":"https://openalex.org/keywords/superacid-catalysis"},{"display_name":"stable carbocations","id":"stable-carbocations","score":0.749,"url":"https://openalex.org/keywords/stable-carbocations"},{"display_name":"aluminum bromide","id":"aluminum-bromide","score":0.2024,"url":"https://openalex.org/keywords/aluminum-bromide"},{"display_name":"aluminum chloride catalysis","id":"aluminum-chloride-catalysis","score":0.2321,"url":"https://openalex.org/keywords/aluminum-chloride-catalysis"},{"display_name":"carbocation structure","id":"carbocation-structure","score":0.4459,"url":"https://openalex.org/keywords/carbocation-structure"},{"display_name":"aromatic alkylation","id":"aromatic-alkylation","score":0.3035,"url":"https://openalex.org/keywords/aromatic-alkylation"},{"display_name":"norbornyl cation","id":"norbornyl-cation","score":0.3438,"url":"https://openalex.org/keywords/norbornyl-cation"},{"display_name":"carbocation chemistry","id":"carbocation-chemistry","score":0.4913,"url":"https://openalex.org/keywords/carbocation-chemistry"},{"display_name":"carbocation reactivity","id":"carbocation-reactivity","score":0.2782,"url":"https://openalex.org/keywords/carbocation-reactivity"},{"display_name":"Friedel-Crafts catalysts","id":"friedel-crafts-catalysts","score":0.2975,"url":"https://openalex.org/keywords/friedel-crafts-catalysts"},{"display_name":"superacid media","id":"superacid-media","score":0.7878,"url":"https://openalex.org/keywords/superacid-media"},{"display_name":"nonclassical carbocations","id":"nonclassical-carbocations","score":0.3161,"url":"https://openalex.org/keywords/nonclassical-carbocations"},{"display_name":"HF/SbF5","id":"hf-sbf5","score":0.6855,"url":"https://openalex.org/keywords/hf-sbf5"},{"display_name":"Friedel-Crafts condensation","id":"friedel-crafts-condensation","score":0.3675,"url":"https://openalex.org/keywords/friedel-crafts-condensation"},{"display_name":"bicyclic carbocations","id":"bicyclic-carbocations","score":0.3234,"url":"https://openalex.org/keywords/bicyclic-carbocations"},{"display_name":"superacidic media","id":"superacidic-media","score":0.6987,"url":"https://openalex.org/keywords/superacidic-media"},{"display_name":"superelectrophiles","id":"superelectrophiles","score":0.5984,"url":"https://openalex.org/keywords/superelectrophiles"},{"display_name":"Friedel-Crafts acetylation","id":"friedel-crafts-acetylation","score":0.2412,"url":"https://openalex.org/keywords/friedel-crafts-acetylation"}],"legacy_keywords":["Superelectrophiles","Superacid-Catalyzed Reactions","Sultam Synthesis","Intramolecular Cyclization","Polymer Synthesis","Aromatic Heterocycles","Asymmetric Synthesis","Lewis Acids","Diels-Alder Reactions","Electrophilic Activation"],"openalex_id":"https://openalex.org/T14068","source_created_date":"2024-01-23T15:27:21","source_updated_date":"2026-10-17T03:02:00","subfield_id":"1607","url":"/topics/T14068","works_api_url":"https://api.openalex.org/works?filter=topics.id:T14068","works_count":25572,"label":"Organic and Inorganic Chemical Reactions","provider":"openalex","revision":"0d7d7e31afb9d74a","taxonomy_revision":"f050b5d4780b1289","title":"Organic and Inorganic Chemical Reactions","kind":"topic-directory","aeo_cohort":"topic-directory","catalogue_revision":"f050b5d4780b1289","numeric_address":"38294617963760725","address_version":"morton4x16-v1","coordinates":[3,16,1607,14068],"answer_status":"Directory metadata; local answer requires separate source review","truth_status":"Subject descriptor, not a factual answer or a demonstrated knowledge gap","reviewed_answer":null}